摘要
使MoCl_5与C_4H_3OCOOH在氯苯溶剂中反应,合成了新的过渡金属钼配合物MoO_2Cl_2(C_4H_3OCOOH)_2。研究了该化合物的红外光谱、紫外-可见光谱、光电子能谱和电氧化还原性质,还用DTA和TG技术研究了它的热分解过程;同时讨论了上述性质与该配合物的结构之间的关系。
The complex MoO_2CI_2(C_4H_3OCOOH)_2 was prepared by the reaction of MoCI_5 with C_4H_3OCOOH in chlorobenzene. The infrared and visible-ultraviolet spectra, XPS and electrochemical properties of title complex were investigated. The processes of thermal decomposition of the coordination were investigated by DTA and TG techniques.
出处
《吉林大学自然科学学报》
CAS
CSCD
1991年第3期99-102,共4页
Acta Scientiarum Naturalium Universitatis Jilinensis
基金
国家自然科学基金委员会资助项目
关键词
钼
络合物
MoCl2
C4H3OCOOH
合成
molybdenum, transition-metal complex, infrared spectra, XPS, visible-ultraviolet spectra, thermogravimetry ciclie voltammetry
