摘要
室温下Pb(OAC)2·3H2O,KNCS,和1,2-双(4-吡啶基)乙烷在甲醇中反应生成了八员环支撑的层状配位聚合物犤Pb(NCS)2(bpea)犦n。三阶非线性Z-扫描研究表明该化合物具有非线性折射行为:其非线性吸收系数α2=1.1×10-11m·W-1,非线性折射系数n2=6.055×10-18m2·W-1。
Under room temperature reaction of Pb(OAc)2·3 H2O with KNCS, 1, 2 bis(4 pyridyl)ethane in CH3OH afforded a novel layered coordinated polymer [Pb(NCS)2(bpea)]n sustained by eight numbered ring units. Investigation of third order optical nonlinearity Z Scan shows that it exhibit considerably nonlinear refractive properties with α2 values of 1.1×10-11m·W-1 and n2 values of 6.055×10-18m2·W-1 respectively.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2001年第4期533-537,共5页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目(No.29631040
No.20001006)。
