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反应工程因素对十二碳烯氢甲酰化反应速率和正异比的影响 被引量:1

EFFECT OF REACTION ENGINEERING FACTORS ON KINETICS AND NORMAL/ISOMERIC ALDEHYDE RATIO OF HYDROFORMYLATION OF 1-DODECENE
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摘要 An orthogonal experiment design is adopted for studying the macroscopic reaction kinetics of hydroformylation of 1-dodecene catalyzed by water-soluble rhodium complex. The experimental data of reaction rate and n∶i aldehyde ratio are analysed by margin and variance analyses. The optimal hydroformylation reaction conditions are suggested by compromise of initial reaction rate and normal/isomeric ratio of product aldehyde. An orthogonal experiment design is adopted for studying the macroscopic reaction kinetics of hydroformylation of 1-dodecene catalyzed by water-soluble rhodium complex. The experimental data of reaction rate and n:i aldehyde ratio are analysed by margin and variance analyses. The optimal hydroformylation reaction conditions are suggested by compromise of initial reaction rate and normal/isomeric ratio of product aldehyde.
出处 《化工学报》 EI CAS CSCD 北大核心 2001年第7期572-574,共3页 CIESC Journal
基金 国家自然科学基金 (No .2 9792 0 74)和SINOPEC联合资助项目&&
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参考文献2

  • 1Chen Hua,J Mol Catal A,1999年,149卷,1页
  • 2Zhang Yongqiang,Catal Today

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