摘要
The title compound was prepared by mixing the aqueous solution of carbohydrazide and manganese perchlorate. It was characterized by X ray diffraction. The crystal of the title compound, [Mn(CHZ) 3](ClO 4) 2, belongs to space group P2 1/n with the crystal parameters a=1.019 7(2) nm, b=0.859 3(1) nm, c=2.141 2(3) nm, β=100.86(1)°; V=1.842 6(5) nm3, Z=4. The results show that all carbohydrazides are coordinated as bidentate by the oxygen atom of the carbonyl group and one nitrogen atom of the end group, forming a distorted octahedron. The explosive properties of the title complex were tested, the application in the engineering detonator was investigated.
The title compound was prepared by mixing the aqueous solution of carbohydrazide and manganese perchlorate. It was characterized by X ray diffraction. The crystal of the title compound, [Mn(CHZ) 3](ClO 4) 2, belongs to space group P2 1/n with the crystal parameters a=1.019 7(2) nm, b=0.859 3(1) nm, c=2.141 2(3) nm, β=100.86(1)°; V=1.842 6(5) nm3, Z=4. The results show that all carbohydrazides are coordinated as bidentate by the oxygen atom of the carbonyl group and one nitrogen atom of the end group, forming a distorted octahedron. The explosive properties of the title complex were tested, the application in the engineering detonator was investigated.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2001年第6期895-897,共3页
Chemical Journal of Chinese Universities
关键词
高氯酸锰
碳酰肼
制备
晶体结构
爆炸性能
起爆药
含能材料
Manganese perchlorate
Carbohydrazide
Preparation
Crystal structure
Explosive properties
