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一种表面具有自由羧基的CdS纳米团簇 被引量:7

A Kind of CdS Nanocluster with Free Carboxyl Groups on Its Surface
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摘要 CdS nanoclusters were directly synthesized in aqueous solution by using mercaptoacetic acid as the stabilizer. The results of TEM(Transmission Electron Microscopy) and ED(Electron Diffraction) show that the structures and aggregations of the resulting CdS nanoclusters can be affected by the molar ratio of mercaptoacetic acid and Cd 2+ ion. When the ratio was high, the resulting nanoclusters were observed as densely packed layer structure on the template. When the ratio was low, the prepared CdS nanoclusters can not form highly aggregated structure. Fluorescence spectra of the CdS nanoclusters show a strong yellow fluorescence. CdS nanoclusters were directly synthesized in aqueous solution by using mercaptoacetic acid as the stabilizer. The results of TEM(Transmission Electron Microscopy) and ED(Electron Diffraction) show that the structures and aggregations of the resulting CdS nanoclusters can be affected by the molar ratio of mercaptoacetic acid and Cd 2+ ion. When the ratio was high, the resulting nanoclusters were observed as densely packed layer structure on the template. When the ratio was low, the prepared CdS nanoclusters can not form highly aggregated structure. Fluorescence spectra of the CdS nanoclusters show a strong yellow fluorescence.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2001年第8期1397-1399,共3页 Chemical Journal of Chinese Universities
基金 吉林省科学技术委员会自然科学基金 (批准号 :990 5 44)
关键词 纳米团簇 巯基乙酸 荧光光谱 硫化镉 水相合成 免疫分析 荧光探针 临床检验 CdS Nanocluster Mercaptoacetic aicd Fluorescence spectroscopy
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