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固体超强酸SO_4^(2-)-MoO_3-TiO_2的制备及其催化酯化性能研究 被引量:22

STUDY ON CATALYTIC PERFORMANCE OF SO_4^(2-)-MoO_3-TiO_2 IN ESTERIFICATION
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摘要 In this paper a new solid superacid catalyst SO 2- 4 MoO 3 TiO 2 was prepared.The activity of the catalyst in esterification of acetic acid and iso amyl alcohol was measured and compared with that of SO 2- 4 TiO 2 and MoO 3 TiO 2.The results showed that SO 2- 4 MoO 3 TiO 2 had better catalytic performance than SO 2- 4 TiO 2 and MoO 3 TiO 2.There was evident coordination between MoO 3 and SO 2- 4 when they coexisted on TiO 2. In this paper a new solid superacid catalyst SO 2- 4 MoO 3 TiO 2 was prepared.The activity of the catalyst in esterification of acetic acid and iso amyl alcohol was measured and compared with that of SO 2- 4 TiO 2 and MoO 3 TiO 2.The results showed that SO 2- 4 MoO 3 TiO 2 had better catalytic performance than SO 2- 4 TiO 2 and MoO 3 TiO 2.There was evident coordination between MoO 3 and SO 2- 4 when they coexisted on TiO 2.
出处 《化学研究与应用》 CAS CSCD 北大核心 2001年第3期290-292,共3页 Chemical Research and Application
基金 湖南省教委青年项目资助课题 !(99B15 )
关键词 固体超强酸 催化酯化 乙酸异戊酯 催化活性 催化剂 硫酸 三氧化钼 二氧化钛 SO 2- 4 MoO 3 TiO 2 solid superacid catalytic esterification iso amyl acetate
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