摘要
许多标准热力学量可从标准化学势 μ — 和热力学函数之间的关系通过数学手段得到 .本文表述了气相反应、凝聚相反应和多相反应的标准平衡常数 ,说明了压力和组成等因素对标准平衡常数的影响 .
Standardthermodynamicequationsmaybeobtainedfromtherelationshipbetweenstandard chemicalpotentialandthermodynamicfunctionsbymathematicsmethod .Inthispaperdefinitionforstan dardequilibriumconstantinthestatesofthegasreaction ,condensedphasereaction ,andmulti- phasereac tionisdefined .Theeffectofpressureandcompositiononstandardequilibriumconstantsisdiscussed .