摘要
The EPR parameters D, g ∥ and g ⊥ are calculated for Ni 2+ occupying two different Cd 2+ sites in CsCdCl 3 crystal using the high order perturbation formulas of EPR parameters of 3d 8 ions in trigonal symmetry. The results obtained from Ni 2+ occupying Cd 2+(I) site show good agreement with the experimental data, while those from Ni 2+ occupying Cd 2+(II) site do not. So, we suggest that Ni 2+ occupy Cd 2+(I) site in CsCdCl 3 crystal.
The EPR parameters D, g ∥ and g ⊥ are calculated for Ni 2+ occupying two different Cd 2+ sites in CsCdCl 3 crystal using the high order perturbation formulas of EPR parameters of 3d 8 ions in trigonal symmetry. The results obtained from Ni 2+ occupying Cd 2+(I) site show good agreement with the experimental data, while those from Ni 2+ occupying Cd 2+(II) site do not. So, we suggest that Ni 2+ occupy Cd 2+(I) site in CsCdCl 3 crystal.
出处
《四川大学学报（自然科学版）》
CAS
CSCD
北大核心
2001年第4期593-595,共3页
Journal of Sichuan University(Natural Science Edition)
