摘要
在直径 50mm的催化反应精馏塔中 ,用活性炭固载硅钨酸作固定床进行合成环己烯的研究 .催化剂在反应条件下显示出很高的活性和良好的选择性 .同时 ,考察了液相连续催化和气相连续催化的主要工艺参数和催化剂种类、塔径高比及催化剂厚度对产物选择性的影响 .实验表明 ,硅钨酸固定床催化精馏合成环己烯 ,催化活性高 ,选择性好 ,环境污染小 ,适于工业连续生产 .
In catalytic reaction rectification column with a diameter of 50 mm, process of synthesis cyclohexene has been investigited by acticarbon adsorb silicotungstic acid. In the recation condiations,catalyst has high activity and selectivity. In this time, the main process parameters of the liquid phase continuous distillation and gas phase continuous catalysis-rectification system and the effect of the reaction with kinds of the catalyst, rectification column diameter-high ratio,catalyst high are examined. It is shown that silicotungstic acid fixed bed catalysis rectification system has bigest producing ability ,high activity and selectivity and less environmental pollution. It can be used in continuous industry production .
基金
湖南省教育厅自科基金资助项目!( 98B0 84)
