硬软酸碱原理与Baeyer-Villiger重排反应

HARD AND SOFT ACIDS AND BASES THEORY AND BAEYER-VILLIGER REARRANGEMENT REACTION

本文应用硬软酸碱原理对Baeyer-Villiger重排反应选择性规律进行理论解释,并说明了异丙苯氧化酸性水解重排反应也遵循硬软酸碱原理。

In this paper, the regulation of Baeyer-Villiger rearrangement reaction selectivity are theoreticaly explained with Hard and Soft Acids and Bases Theory, and explained that the rearrangement reacton of isopropyl benzene oxidized and acid hydrolysis also follous Hard and Soft Acids and Bases principle.