Bi_2O_3-Li_2O玻璃的热致变色研究

STUDY ON THE THERMOCHROMIC PROPERTIES OF Bi_2O_3-Li_2O GLASSES 

发现氧化和氧化锂所形成的玻璃有着明显的热致变色现象 .温度系数随氧化含量的增加而上升 ,反映了热致变色现象主要来源于氧化 .这种热致变色现象与半导体同样 ,来源于玻璃中的电子 声子相互作用而产生的随温度变化的光学能隙 .氧化重金属氧化物玻璃中高电子密度和低声子能量的化学键是产生强电子

Reversible thermochromic properties were observed in Bi2O3-Li2O system glasses. The temperature coefficient of optical absorption edge increases with increasing Bi2O3 content, implying that Bi2O3 is the main reason of thermochromism. The thermochromic mechanism is explained in terms of the temperature dependence of the optical energy gap E-g, caused mainly by the electron-phonon interaction. The low phonon energy and high electron density of Bi-O bond are important factors contributing to the electron-phonon interaction in these glasses.