摘要
用终产物分析的方法研究了环己烷 (CH) -三辛基氧化膦 (TOPO)体系在γ辐解过程中环己烷激发态能量传递的速率常数。结果表明 ,此过程中激发能传递的速率常数为 1.9× 10 10 L·mol·s- 1。
The rate constant of excited energy transfer in the γ radiolysis of CH-TOPO system was studied by final product analysis. The results showed that the rate constant for the system was 1.9×10 10 L·mol·s -1 , which was a little larger than that of an ordinary diffusion-controlled process.
出处
《辐射研究与辐射工艺学报》
CAS
CSCD
北大核心
2001年第1期32-35,共4页
Journal of Radiation Research and Radiation Processing
基金
核科学基金项目! (H7196NY0 0 2 )
关键词
环已烷
三辛基氧化膦
扩散控制
终产物分析
激发态
能量传递
速率常数脉冲辐解
Cyclohexane (CH), Trioctyl phosphine oxide (TOPO), γ radiolysis,Energy transfer,Diffusion-controlled, Abnormal rate constant
