摘要
以 Ni2 + 作模板 ,通过间苯二甲醛与二乙烯三胺进行 1 +1成环缩合 ,得到了一种 Ni2 + 的大环配合物 ,经过还原、去模板以及质子化反应得到了 3,6,9-三氮杂双环 [9,3,1 ]-十五 -1 ,1 1 ,1 3-三烯的氢溴酸盐。经元素分析、红外光谱、核磁共振谱和差热分析对其结构进行了表征。结果表明 。
A new macrocyclic compound was synthesized and characterized by (1+1) cyclic condensation between 1,3 diformylbenzene and diethyltriamine followed by reduction and demetalization reactions separately.The structure of the compound was characterized by elemental analysis,IR and 1HNMR spectra.The results indicated that the compound contains crystal water and alcohol molecules.
出处
《化学试剂》
CAS
CSCD
北大核心
2001年第4期229-231,共3页
Chemical Reagents
