摘要
制备了一种表面带负电的胶态纳米银 ,用透射电镜、吸收光谱、SERS谱对该纳米银进行了研究。发现纳米银的粒径分布均匀 ,平均粒径为 11nm ,吸收峰为 4 2 2nm ,常温下放置 7个月仍具有较强的SERS活性。当阴离子型分子吲哚丁酸、阳离子型分子碱性品红、亚甲兰及中性分子邻菲罗邻分别吸附在其上时 ,观察到阳离子型分子碱性品红和亚甲兰及中性分子邻菲罗邻的SERS谱 。
Negatively charged colloidal nano-silver particles were successfully prepared by the colloidal chemical method. A 1.7% solution of silver nitrate (2 mL) was diluted with deionized water to 100 mL. A 1% solution of tannic acid (1 mL) was added dropwise to the solution stirring, then a 1% solution of potassium carbonate anhydrous (3~4 drops) was added to the mixed solution. Finally ,a red-brown silver sol was obtainned,which was stable at room temperature for seven months. It has been testified that the silver sol is a negatively charged colloid by experiment of electrophoresis. The sizes of particles were determined by Hitachi H-800 transmisson electron microscope. Absorption spectroscopy and SERS were used to determine of the main properties. Absorption spectroscopy was obtained with UV-1201. Raman spectra were recorded with RENISHAW MIK 1000 Raman micro-spectroscopy. The 514.5 nm line of an argon ion laser with about 3 mW was used. It has been found that the mean diameter of the particles was 11 nm; it had absorption maximum at 422 nm; Strong SERS spectra were observed when cationic molecules of fuchsin basic and methylene blue and neutral molecule of 1,10-phenanthroline were adsorbed on it respectively, but no SERS for the anionic molecule of Indolebutyric acid.
