二（2—苯并咪唑亚甲基）胺合Zn（Ⅱ）配合物晶体和电子结构研究及生物活性测定

Synthesis, Crystal and Electronic Structure, and Activities of Zinc Complexes of N, N- bis(benzimidazol- 2- ylmethyl)amine

合成了二(2-苯并咪唑亚甲基)胺合Zn(Ⅱ)高氯酸盐配合物[C16H15N5Zn@(C1O4)2@3H2O和C32H30N10Zn@(ClO4)2@C2H5OH],进行了元素分析、红外和紫外表征.对后者采用X射线方法测定了晶体结构,并采用G94W程序进行了量子化学计算.利用邻苯三酚自氧化法测定了所合成配合物的生物活性.

The complexes of N,N - bis(benzimidazol-2-ylmethyl) amine with zinc(II), C16H15N5Zn (ClO4)(2). 3H(2)O (A) and C32H30N10Zn . (ClO4)(2).C2H5OH (B), were synthesized and characterized with element analysis, UV, and IR spectroscopy. The crystal structure of (B) was determined by X-ray diffraction. Quantum chemistry computation was also performed on the these compounds using G94W program. Biological activities of the complexes were measured by means of pyrogallol autoxidation.