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Mg-Al-MMH-高岭土分散体系触变性研究 被引量:21

Studies on the Thixotropy of Magnesium Aluminum Hydroxide-Kaolinite Suspension
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摘要 The thixotropy of suspension, the rheological properties change with the increase of shear time, is a complicated rheological phenomenon. The shear thinning and the shear thickening phenomena, i.e ., positive thixotropy and negative thixotropy, were observed respectively in the previous studies. Recently we found a novel thixotropic phenomenon, described as "complex thixotropy", during studying the thixotropic phenomenon of magnesium aluminum hydroxide montmorillonite suspension. The study of thixotropy of the aqueous suspension consisting of magnesium aluminum hydroxide(Mg Al MMH)possessing permanent positive and Kaolinite possessing permanent negative charges is reported. The suspensions studied may display a positive thixotropy and complex phenomenon successively in various Mg Al MMH/kaolinite ratios 0-0.16 examined. The effect of shear rate( D L)used in measuring viscosity on the thixotropy of the suspension was investigated, and the mechanism of the thixotropy was discussed. The thixotropy of suspension, the rheological properties change with the increase of shear time, is a complicated rheological phenomenon. The shear thinning and the shear thickening phenomena, i.e ., positive thixotropy and negative thixotropy, were observed respectively in the previous studies. Recently we found a novel thixotropic phenomenon, described as 'complex thixotropy', during studying the thixotropic phenomenon of magnesium aluminum hydroxide montmorillonite suspension. The study of thixotropy of the aqueous suspension consisting of magnesium aluminum hydroxide(Mg Al MMH)possessing permanent positive and Kaolinite possessing permanent negative charges is reported. The suspensions studied may display a positive thixotropy and complex phenomenon successively in various Mg Al MMH/kaolinite ratios 0-0.16 examined. The effect of shear rate( D L)used in measuring viscosity on the thixotropy of the suspension was investigated, and the mechanism of the thixotropy was discussed.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2001年第9期1578-1580,共3页 Chemical Journal of Chinese Universities
基金 国家自然科学基金 (批准号 :2 98730 2 6 )资助
关键词 混合金属氢氧化物 高岭土 触变性 分散体系 层状二元氢氧化物 流变学 Mg-Al-MMH-高岭土 Mixed metal layered hydroxide Kaolinite Thixoropy Suspension Layered double hydroxides
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