胶束中的若丹明6G荧光增强和激光行为

Fluorescence Enhancement and Laser Behavior of Rhodamine 6G in Micell

使用阴离子表面活性剂十二烷基硫酸钠 (SDS)有效的增强了若丹明 6G染料水溶液的荧光 ,在若丹明 6G浓度分别为 5 47× 10 -7和 5 47× 10 -4 mol·L-1时 ,最大增强比率分别为 1 95和 9 7。在后一浓度下SDS的加入使若丹明 6G染料激光阈值降低 ,能量转化效率提高。不加SDS时的激光阈值功率密度约为 6 5MW·cm-2 ,加入 4 1× 10 -2 mol·L-1的SDS后 ,激光阈值功率密度降为 0 8MW·cm-2 。泵浦光功率密度为 6 5MW·cm-2 时 ,能量转化效率达到 2 5 %。同时还观察到SDS的加入使溶液吸收谱、荧光谱和染料激光发生了红移。对以上现象的物理机制进行了讨论。

Fluorescence of Rhodamine 6G in aqueous solution is effectively enhanced by using anionic sodium dodecylsulfate (SDS) surfactant. When the concentration of Rhodamine 6G is 5.47 X 10(-7) mol (.) L-1 and 5.47 x 10(-4)mol (.) L-1 ,maximal enhancement ratio can be 1. 95 and 9. 7, respectively. In the latter case, using SDS can reduce the threshold and improve the energy conversion efficiency of the dye laser of Rhodarnine 6G. In the absence of SDS, the laser threshold power density is near 65 MW cm(-2). While in the present of SDS, the threshold is reduced to 0. 8 MW. CM-2 . The laser energy conversion efficiency can reach 25 % when the pumping power density is 65 MW (.) cm(-2). We also observed the red shifts of absorption spectrum, fluorescence spectrum and the dye laser spectrum in the present of SDS. The physical mechanism of the phenomena is discussed.