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海洋沉积物中多环芳烃的分离和测定 被引量:1

SEPARATION AND DETERMINATION OF POLYCYCLIC AROMATIC HYDROCARBONS IN MARINE SEDIMENTS
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摘要 多环芳烃(Polycyclic Aromatic Hydrocarbons,PAH)组分中,大多数具有致突变和致癌性。大气、土壤等自然环境中已经检测出了多种多环芳烃。近年来,在河流、内湾及沿岸海域的水体、沉积物中,也检测出了各种多环芳烃。多环芳烃在海洋环境中广泛存在,已经引起了人们的普遍重视。 The wide existence of PAHs in marine environment have caused great concern. Many analytical methods for separation and determination of PAHs in marine environment have been developed.In this paper, Soxhlet extraction and column chromatography were employed to separate the PAHs in marine sediment. The determination of PAHs was made by capillary gas chro-matograph. Identification and quantum of the chromatographic peak were also conducted by utilizing PAHs standards and GC/MS.The recover rate of PAHs standards by this method was in the range of 72-101%. Twenty PAHs were separated and determined in the surface sediment of Tokyo Bay.
作者 余顺
出处 《海洋与湖沼》 CAS CSCD 北大核心 1989年第4期387-391,共5页 Oceanologia Et Limnologia Sinica
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  • 1朱桂海,李英,程忠权.杭州湾沉积物中油浓度分布特征及其来源探讨[J].海洋环境科学,1994,13(2):32-39. 被引量:4
  • 2林伟生,王国俊,俞惟乐.自制超临界流体萃取仪操作条件的优化及其应用[J].分析化学,1995,23(7):765-769. 被引量:14
  • 3余顺.东京湾及河口区表层沉积物中污染物行为的研究——Ⅱ.多环芳烃的行为及其来源[J]海洋环境科学,1988(04).
  • 4Zheng Jinshu and James GQ.Analyticalproceduresto classify organicpollutantsin naturalwaters,sedimentsand benthic organisms. Acta Oceanologica Sinica . 1998
  • 5Ronald AH,Laflamme REand FarringtonJW.Sedimentary polycyclic aromatic hydrocarbons:the historicalrecord. Science . 1977
  • 6Bigot M,etal.Organicgeochemistryofsurfacesedimentsfrom the Huanghe estuaryandagacent Bohaisea. Chemical Geology . 1989
  • 7Reimer G,etal.Comparison ofSFEandsoxhletextractionforthe analysisofnative PAHsin soils. JChromatogr,A . 1995
  • 8Walter ER.Molecularcompositionsof weathered petroleum and comparison withits possible source. Geochimica et Cosmochimica Acta . 1977
  • 9Blanco CG,PradoJG,Guillen MD,etal.Preliminaryresultsofextractioninsoilshale. Organic Geochemistry . 1992
  • 10马永安,刘彤,赵云英.色谱/质谱(GC/MS)联用技术分析测定海藻中的石油烃和多环芳烃[J].海洋通报,1997,16(6):80-85. 被引量:6

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