稀土与混合配体配合物的研究——Ⅵ.2—羟基—3—萘甲酸(H_2A)、邻菲咯啉(Phen)与稀土(RE)三元固体配合物的合成及性质

Study on Ternary Complexes of Rare Earth Elements Ⅳ.Syntheses and Properties of Ternary Complexes of Eare Earth Elements with 2-Hydroxy-3-Naphthoic Acid and Phenantholine

本文报道了稀土与2—羟基—3—荼甲酸(H_2A)、邻菲咯啉(Phen)三元固体配合物的合成方法.通过化学和元素分析,IR,UV,~1HNMR,X射线粉末衍射、摩尔电导,磁化率、差热等对所合成的配合物进行了结构、组成和性质的研究.

Nine ternary complexes of rare earth elements with 2-hydroxy-3-naphthoic acid (H_2A) and phenanthroline (Phen) are synthesized. Theirchemical analysis, elementary analysis, molar conductance, magneticsusceptibility and TG are carried out and studied.