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TiO_2-KNO_3溶液界面吸附K^+和NO_3^-的本征络合常数 被引量:1

Determination of Intrinsic Complexation Constants of NO_3^- and K^+ at TiO_2-KNO_3 Aqueous Interface
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摘要 根据TiO2 表面羟基二元酸的假定 ,应用电位滴定实验数据 ,利用外推作图法求出了TiO2 表面吸附K+和NO3- 的本征络合常数。该数据不仅反映了TiO2 对电解质离子的络合能力 ,也反映了其表面酸性。 Intrinsic complexation constants of NO 3 - and K + at TiO 2-KNO 3 aqueous solution interface are determined, which show not only the acidity of TiO 2, but also the strength of complexation of the ions
作者 熊艰
机构地区 上饶师范学院
出处 《上饶师范学院学报》 2001年第3期58-61,共4页 Journal of Shangrao Normal University
关键词 界面化学 平衡常数 二氧化钛 硝酸钾 本征络合常数 界面吸附 TiO_2 Interface Chemistry Complex Equilibrium Constant
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  • 1[1]Schindler P W.Surface Complexes at Oxide-Water Interfaces[A].Andern M A.& Rubin A J.Adsorption of Inorganics at Solid-liquid Intefface[C].Michigan:Ann Arbor Science Publishers' Inc.,1981.1-50.
  • 2[2]Huang C P & Stumm W.Specific Adsorption of Cationson Hydrous γ-Al2O3[J].J.Coll.Inteff.Sci.,1973,43:409.
  • 3[3]Davis J A,James R O & Leckie J O.Surface Ionization and Complexation at the Oxide/Water Interface[J].J.Coll.Interf.Sci.,1978,63: 480.

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同被引文献6

  • 1Parks G A.Aqueous Surface Chemistry of Oxides and Complex OxideMinerals[J],Adv.Chem.Ser.,1967; (67):121.
  • 2Huang C P & Stumm W.Specific Adsorption of Cations on Hydrous γ-Al2O3 [J],J.Coll.Interf.Sci.,1973; (43) :409.
  • 3Yates D E,Levine S & Healy T W.Site-BindingModel of the Electric Double Layer at the Oxide-Water Interface[J].Chem.Soc.Faraday Trans.I,1974; (70):1807.
  • 4Metigevic E.Principles and Application of Water Chemistry[M],New York:Wiley,1967.
  • 5James R.O.Surface Ionization and Complexation at the Colloid/Aqueous Electrolyte Interface[ J].in "Adsorption of Inorganics at SolidLiquid Interface"[M].by Ann Arbor Science Publishers,Inc.,Ann Arbor,Michigan,1981.
  • 6熊艰.TiO_2表面本征酸常数的测量[J].上饶师专学报,2000,20(3):49-54. 被引量:2

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