离子反极化效应的普遍性

On the Universality of Ion Contra-polarization Effects

提出:离子反极化效应在含三个以上离子晶体中应当是普遍存在的。(1)通过论述证明了在一些无机酸中存在离子反极化效应。解释了酸性强弱的规律性,以及磷的含氧酸酸性反常现象。(2)论述了金属氢氧化物中存在离子反极化效应。提出了反极化作用是随中心离子半径的减少,电荷增多或惰气型金属离子被非惰气型金属离子取代时而增大,其碱性减弱。(3)在一些晶体的无机含氧酸盐中也存在反极化效应。

The author advances a new theory:ion contra-polarization effect should exist universality triprotic or over triprotic ion crystal. 1.The existence of ion coutra-polarization effect in triprotic inorganic acid is proved by means of exposition.The effect can explain the regularity of acidity on intensity or weakness,which is already proved with value Ka.It can also clarify the regularity of phosphorus' oxygen acidity abnormality. 2.The existence of ion cotrna-polarizaotin effect in metal hydroxide si proved by means of exposition.It puts forward that the polarization function will be bigger with the fact that the central ion radius becomes smaller,electric charge increases or non-inert gases mteal ion substitutes for inert gases metal ion.While metal hydroxide alkalinity weakens.It can also explain the regularity of hydroxide to heat stability. 3.Ion contra-polarization effect also exists in inorganic oxysalt of triprotic crystal.It can illustrate the differences of alkaline-earth metal carbonate from the heat stability.