摘要
报道了含配体 N,N—二 (2 -苯并咪唑甲基 )亚胺 (简写为 IDB)的镍配合物〔Ni(IDB) 2 〕(Cl O4 ) 2 ·CH3 CH2 OH· H2 O( )的合成 ,对 ( )进行了元素分析、摩尔电导、紫外——可见光谱、红外光谱、自旋共振谱研究 ,推测配合物 ( )的中心离子镍 ( )为六配位的八面体结构。
A mononuclear nickel(Ⅱ)complex〔Ni(IDB) 2〕·(ClO 4) 2·CH 3CH 2OH·H 2O(Ⅰ) is reported(The tridentate ligand IDB is 〔N,N-di(2-benzimidazolyl-methyl)imino〕),The elemental analyses?molar conductivity?ultraviolet and visible(UV-Vis)?infrared(IR).electron spin resonance(ESR) of the complex has been studied.The nickel(Ⅱ) atom in the cation of the complex has distorted octahedronal coordination geometry and is sixcoordinated by six nitrogen atoms:four nitrogen atoms of benzimidazole groups and two imine nitrogen atoms from the ligand IDB.
出处
《湖北师范学院学报（自然科学版）》
2001年第3期69-71,共3页
Journal of Hubei Normal University(Natural Science)
关键词
合成
表征
镍
单核配合物
synthesis
characterization
mononuclear nickel(Ⅱ)complex
