摘要
综述了茂金属与非茂金属催化剂引发丁二烯聚合的研究进展。茂钒催化剂在丁二烯聚合中有较高的催化活性，聚合物顺－ 1,4－结构摩尔分数约为 80％， 1,2－结构摩尔分数约为 20％。
The researches and developments on metallocene and non - metallocene catalystic system for 1, 3-butadiene polymerization were reviewed with 26 references. The cyclopentadienyl derivatives of vanadium activated by MAO showed the highest of all the known catalytic systems regarding polymerization of butadiene. The mole fraction of cis - 1, 4-unit was about 80% and 1, 2-unit about 20%.
出处
《合成橡胶工业》
EI
CAS
CSCD
北大核心
2001年第5期310-315,共6页
China Synthetic Rubber Industry
