三氯化锑和二氧杂环己烷配合物[SbCl_3·{(CH_2)_4O_2}_(1.5)]的合成与晶体结构(英文)

Synthesis and Crystal Structure of t he Complex of Antimony Trichloride and Dioxane

New solid complex of the antimony trichloride and dioxane was obtained th rough a reaction of the dioxane and the absolute methanol solution of the antimony trichloride.The formula of the complex is[SbCl3·｛(CH2)4O2｝1.5].The crystal structure of the comple x belongs to cubic system,space group I-43d,a=17.1417(5)?,Z =16.The trivalent antimony ion n ot only bonds directly to three chlorine anions,but also is co ordinated by three oxygen atoms of th e dioxane molecules.Two oxygen atoms in a dioxane molecule wi ll coordinate to different antimony ions,respectively.

New solid complex of the antimony trichloride and dioxane was obtained through a reaction of the dioxane and the absolute methanol solution of the antimony trichloride. The formula of the complex is [SbCl3 . {(CH2)(4)O-2}(1.5)]. The crystal structure of the complex belongs to cubic system, space group I-43d, a = 17.1417 (5) Angstrom, Z = 16. The trivalent antimony ion not only bonds directly to three chlorine anions, but also is coordinated by three oxygen atoms of the dioxane molecules. Two oxygen atoms in a dioxane molecule will coordinate to different antimony ions, respectively.