摘要
New solid complex of the antimony trichloride and dioxane was obtained th rough a reaction of the dioxane and the absolute methanol solution of the antimony trichloride.The formula of the complex is[SbCl3·{(CH2)4O2}1.5].The crystal structure of the comple x belongs to cubic system,space group I-43d,a=17.1417(5)?,Z =16.The trivalent antimony ion n ot only bonds directly to three chlorine anions,but also is co ordinated by three oxygen atoms of th e dioxane molecules.Two oxygen atoms in a dioxane molecule wi ll coordinate to different antimony ions,respectively.
New solid complex of the antimony trichloride and dioxane was obtained through a reaction of the dioxane and the absolute methanol solution of the antimony trichloride. The formula of the complex is [SbCl3 . {(CH2)(4)O-2}(1.5)]. The crystal structure of the complex belongs to cubic system, space group I-43d, a = 17.1417 (5) Angstrom, Z = 16. The trivalent antimony ion not only bonds directly to three chlorine anions, but also is coordinated by three oxygen atoms of the dioxane molecules. Two oxygen atoms in a dioxane molecule will coordinate to different antimony ions, respectively.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2001年第6期901-904,共4页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目(No.29771011)