富勒烯的杯芳烃包合物的研究现状与展望

Researches on the Inclusion Complex of Fullerene and Calixarene:Current Status and Prospects

介绍了[60/70]富勒烯与杯[8],[6],[5]芳烃、高氧杂杯[3]芳烃及双杯芳烃形成包合物的研究进展和应用前景.

Fullerenes have globular structures with external pi -electron surfaces, whereas calixarens have cavity structures with internal pi -electron surfaces. They could bind to each other by guest-host complexation. through pi-pi interactions. In this paper, an overview of the complexation of fullerenes with various calixarene-based receptors including calix[8]arenes, calix[6]arenes, calix[5]arenes, homooxacalix[3]renes, calix[4]arenes and bridged biscalix[n]arenes along with their preparations, structures, properties and applications is provided.