硫代杯[4]芳烃与镍、铜、银配合物的合成与表征

SYNTHESIS AND CHARATERIZATION OF THE COMPLEXES OF NICKEL, COPPER, SILVER WITH A THIACALIXARENE

以硫代亚甲桥对叔丁基杯 [4 ]芳烃为配体 ,以三氯甲烷与乙腈为混合溶剂合成了过渡金属镍、铜、银的杯芳烃金属配合物。由元素分析确定配合物的组成为Ni(C4 0 H4 8O4 S4 ) 2 (NO3 ) 2 ,Cu(C4 0 H4 8O4 S4 ) 2 (NO3 ) 2 ,Ag2 C4 0 H4 6 O4 S4 ,利用红外光谱、紫外光谱对配合物进行了表征 .

Three new complexes of p-tert-butylthiacalixarene with copper, silver, nickel are prepared. Their compositions are determined as Ni(C 40 H 48 O 4S 4) 2(NO 3) 2, Cu(C 40 H 48 O 4S 4) 2(NO 3) 2 and Ag 2C 40 H 46 O 4S 4, by elemental analysis respectively. Their properties are studied by UV and IR spectra.