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新型环磷腈基聚合物的合成 被引量:3

Synthesis of new cyclomatrix polymers on octachlorocyclotetraphosphazene
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摘要 以八氯环四磷腈和一缩二乙二醇、二缩三乙二醇为原料,二氧六环做溶剂,在金属钠和碳酸钠存在下,制备出聚(一缩二乙二醇氧基环四磷腈[P4N4Cl4(OCH2CH2OCH2CH2O)4]n和聚(二缩三乙二醇氧基环四磷腈)[P4N4Cl4(OCH2CH2OCH2CH2OCH2CH2O)4]n,并对其进行了表征. Two new cyclomatrix polymers, poly (triethylene glycol cyclotetraphosphazene) and poly (diethylene glycol cyclotetraphosphazene) were synthesized, from octachlorocyclotetraphosphazene diethylene glycol, triethylene glycol sodium, and sodium carbonate as proton absorber, in 1, 4- Dioxane solvent.
出处 《黑龙江大学自然科学学报》 CAS 2001年第3期95-97,103,共4页 Journal of Natural Science of Heilongjiang University
基金 黑龙江省自然科学基金资助项目(E9610)
关键词 合成 八氯环四磷腈 聚(一缩二乙二醇氧基环四磷腈) 聚(二缩三乙二醇氧基环四磷腈) 环磷腈基聚合物 synthesis octachlorocyclotetraphosphazene poly (triethylene glycol cyclotetraphosphazene) poly (Diethylene glycol cyclotetraphosphazene)
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参考文献5

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同被引文献15

  • 1高坡,朱宇君,袁福龙.六氯环三磷腈基类聚合物的合成[J].哈尔滨工业大学学报,2006,38(5):770-772. 被引量:8
  • 2Allcock H R. Chemistry and applications of polyphosphazenes[M]. New York : John Wiley & Sone, 2003: 3-7.
  • 3Rose S H, Reynard K A. Curable fluorophosphazene polymers : USA, US003702833[P]. 1972-11-04.
  • 4Kaskhedikar N, Paulsdorf J, Burjanadze M, et al. Polyphosphazene based composite polymer electrolyte[J]. Solid State Ionics, 2006,177 (13):2699-2704.
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  • 6ALLCOCK H R,KUGEL R L,VALAN K J.Phosphonitrilic compounds.Ⅵ High-molecular-weight poly (alkoxy-and aryloxyphosphazenes)[J].Inorg Chem,1966,5(10):1709 -1715.
  • 7ALLCOCK H R,KUGEL R L.Synthesis of high-polymeric alkoxy and aryloxy phosphonitriles[J].J Am Chem Soc,1965,87:4216 -4217.
  • 8ALLCOCK H R,KUGEL R L.Phosphonitrilic compounds.Ⅶ.High-molecular-weight poly (diaminophosphazenes)[J].Inorg Chem,1966,5:1716-1718.
  • 9YUAN F,ZHU Y J.A modified method for preparation of a pure chlorocyclophosphazene tetramer[J].Phosphorus,Sulfur and Silicon,2001,176(6):77 -81.
  • 10ALLEN C W.Hybrid inorganic -organic polymers derived from organofunctional phosphazenes[J].ACS Symp Ser (Inorg Organnomet Polym),1988,360:290-295.

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