摘要
(E)-ω-氯汞化莰烯和(E)-ω-氯汞化长叶烯在THF中,RhCl_3催化下分别得到了莰烯和长叶烯的对称二聚体。用IR、~1HNMR、^(13)CNMR、UV和MS证明了两个二聚体的结构。
Symmetric dimers of camphene and long ifolene were prepared from ( E) -ω-chloromcrcuricamphene and (E) -ω-chloro mercurilongifolene respectively in the presence of rhodium chloride in THF at room temperature. Their structures were confirmed by IR, UV, 1HNMR. 13CNMR and MS.
出处
《南京林业大学学报(自然科学版)》
CAS
CSCD
1991年第1期54-57,共4页
Journal of Nanjing Forestry University:Natural Sciences Edition
关键词
莰烯
长叶烯
二聚体
Campbene
Longifolene
Dimer