摘要
合成了两种草酰胺桥联的新异双核配合物 [Cu(Me2 oxpn)Mn(phen) 2 ](ClO4 ) 2 (Ⅰ )和 [Cu(Me2 oxpn)Zn(phen) 2 ](Ⅱ )。其中 ,phen代表 1,10 -邻菲罗啉 ;Me2 oxpn为N ,N’ -双 (3 -氨基 - 2 ,2 -二甲基丙基 )草酰胺根阴离子。用元素分析、红外光谱、电子光谱、摩尔电导及磁性测量等方法对配合物进行了表征。
Two new μ-oxamido heterobinuclear complexes [Cu(Me 2oxpn)Mn(phen) 2](ClO 4) 2(Ⅰ) and [Cu(Me 2oxpn)Zn(phen) 2](ClO 4) 2(Ⅱ),where phen stands for 1,10-phenanthroline,Me 2oxpn represents N,N'-bis(3-amino-2,2-dimethylpropyl)oxamido dianion,have been synthesized and characterized by elemental analyses,magnetic moment,molar conductivity measurements and spectroscopy.The effects on the wheat growth of the binuclear complexes are also studied.
