西佛碱型大环多胺镉配合物的合成与表征

Synthesis and Characterization of Transition Metal Cd Complexes of Schiff Base Macrocyclic Polyamine

三乙烯四胺与乙二醛反应得到西佛碱型大环多胺化合物C16H32 N8(L)。配体L经元素分析、红外、紫外 -可见、质谱等确证。在此基础上进一步合成了其与过渡金属离子Cd2 + 的双核配合物 ,对该配合物进行了元素分析、红外、紫外 -可见。

This paper deals with synthesis of transition metal Cd complexes of a new schiff base macrocyclic polyamineseries ligand. The compounds were characterized by elemental analysis, IR,UV-Vis,MS and molar conductance. The measured results show that the composition of the complexes was of 1∶2 type and it is a binuclear hexaazamacrocyclic complex.