抑铬雾剂F—53的研制带动了有机氟化学的发展

Some Progress in Organofluorine Chemistry Promoted by the Preparation of Chromic Acid Mist Suppressant,F-53

回顾了在抑铬雾剂F-53研制的推动下,在(i)亲核试剂进攻下全氟(或多氟)磺酸酯的卜O和/或C-O断裂方式(ii)全氟碘代烷的单电子转移反应(iii)

This review includes the synthesis of perfluoroalkane-sulfonic esters, single electrom-transfer reactions of perfluoroalkyl iodides, difluorocarbene precursors and trifluoromethylation of organic halides. All these reactions are derived from the preparation of chromic acid mist suppressant F-53, CF3(CF2)(5)OCF2CF2SO3K.