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合成甲醇反应器流向变换强制周期操作特性 被引量:5

UNSTEADY-STATE METHANOL SYNTHESIS IN FIXED BED REACTOR OPERATING UNDER FLOW REVERSAL MODE
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摘要 实验研究了合成甲醇固定床反应器流向变换强制周期操作的非定态特性 ,考查了流向变换周期、进料流速和进料组成对床层轴向温度分布、热波在床层内的爬行速度以及反应器流出物组成的影响 .研究发现 ,即使进料中∑COx 总浓度降低至 0 .33 % (mol) 。 Unsteady-state performance of a fixed bed reactor for methanol synthesis, operating under flow reversal mode, was experimentally studied. The effects of various factors, such as feed gas velocity, feed composition and cycle duration on the transient axial temperature profile in the bed, propagation velocity of thermal wave, transient composition of tail gas and time-averaged methanol output were investigated at a pressure of 2.0 MPa, gas velocity about 0.20-0.50 m&middots-1, cycle duration of 20-120 min and total concentration of carbon oxides, ΣCOx, 0.33%-7.32% mol. Higher conversion of ΣCOx than that of steady-state operation was achieved even though for a very low concentration of ΣCOx down to 0.33% mol.
出处 《化工学报》 EI CAS CSCD 北大核心 2001年第12期1054-1057,共4页 CIESC Journal
基金 国家自然科学基金 (No .2 9476 2 2 3) 前化学工业部(No .95 -2 3 -0 1)资助项目~~
关键词 流向变换 强制周期操作 合成 甲醇 反应器 催化剂 Reactor operation Synthesis (chemical) Unsteady flow
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参考文献6

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同被引文献32

  • 1韦军,孙欣欣,张金昌,李成岳.丙烯腈尾气流向变换催化燃烧的实验研究[J].化学反应工程与工艺,2005,21(3):199-204. 被引量:6
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  • 3路勇,沈师孔.甲烷催化部分氧化制合成气研究新进展[J].石油与天然气化工,1997,26(1):6-14. 被引量:36
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