摘要
根据配位矢量和趋于零的假设,计算了TcAB_4型配合物的键角,它与实验值符合得较好,从而印证了空间堆积模型用于Tc化学的可行性。还论述了堆积参数在推测和设计Tc化合物方面的应用。
Bond angles in structures of the coordination pattern TcAB4 are calculated and agree well with those obtained by X-ray diffraction based on the assumption that the vector sum of the coordinating ligands in each structure approaches zero.Thus the usability of the cone packing model to Tc chemistry is confirmed. The utilization of the packing parameters in prediction and design of Tc complex is demonstrated.
出处
《核化学与放射化学》
CAS
CSCD
北大核心
1989年第1期7-12,共6页
Journal of Nuclear and Radiochemistry
基金
国家自然科学基金会资助项目
关键词
键角
锝络合物
空间堆积模型
Bond angle, TcAB4 pattern, Cone packing model, Packing parameter, Tc complex.
