摘要
作为化学反应动力学过程过渡状态的活化给合物 ,实际上处于非平衡定态 .作者根据非平衡态热力学的随机理论 ,对反应速度活化络合物理论涉及的热力学及统计力学问题给予了评论 ;定量地分析了活化络合过程的耗散与涨落对反应速度的影响 。
The activated complex as a transition state in the chemical kinetic processes is actually at a nonequilibrium steady state. By means of the stochastic theory of nonequilibrium thermodynamics the thermodynamical and the statistical problems concerned with the absolute rate theory are commented. The influences of both the dissipation and the fluctuation in activated complexation on the reaction rate are analysed quantitatively. As a result a revised explicit statistical formula of the rate constant has been deduced.
出处
《四川大学学报（自然科学版）》
CAS
CSCD
北大核心
2001年第6期881-884,共4页
Journal of Sichuan University(Natural Science Edition)
基金
国家自然科学基金 (2 0 0 730 2 7)
