摘要
以 (甲基 )丙烯酸羟烷基酯与三氟乙酐反应合成了三种新型含氟单体 :甲基丙烯酸三氟乙酰氧乙酯、丙烯酸三氟乙酰氧乙酯和丙烯酸三氟乙酰氧丙酯 .测定了三种单体的摩尔吸光系数、折光率和密度等参数 ;并通过与苯乙烯进行自由基本体共聚分别测定了三种单体的竞聚率 ,计算了三种单体的Q。
Three novel fluorine-containing monomers: 2-[(trifluoroacetyloxy)]ethyl methacrylate (TFAOEMA), 2-[(trifluroacetyl)oxy]ethyl acrylate (TFAOEA), and 2-[(trifluroacetyl)oxy]propyl acrylate (TFAOPA), were successfully synthesized. Radical copolymerization of TFAOEMA, TFAOEA or TFAOPA with styrene were carried out in bulk. The monomer reactivity ratios were then determined. And the Q, e values of the three novel monomers were calculated. Moreover, the molar absorption coefficients, refractive indexes and densities of TFAOEMA, TFAOEA and TFAOPA were mjeasured.
出处
《南开大学学报（自然科学版）》
CAS
CSCD
北大核心
2001年第4期13-17,23,共6页
Acta Scientiarum Naturalium Universitatis Nankaiensis
基金
德国BASF公司资助
