摘要
Coordination complexes derived thiosemicarbazone ligands were designed to exhibit the potential factors to influence the molecular packing. The aromatic group 4,5 diazafluorene can form strong hydrogen bonds with the lattice water molecules from which connect the molecules aggregating into a one dimensional screw chain. It seems that the existence of those hydrogen bonds is essential for the molecules crystallized in noncentral space group and exhibiting obviously SHG efficiency.
Coordination complexes derived thiosemicarbazone ligands were designed to exhibit the potential factors to influence the molecular packing. The aromatic group 4, 5-diazafluorene can form strong hydrogen bonds with the lattice water molecules from which connect the molecules aggregating into a one-dimensional screw chain. It seems that the existence of those hydrogen bonds is essential for the molecules crystallized in noncentral space group and exhibiting obviously SHG efficiency.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2002年第1期112-114,共3页
Chinese Journal of Inorganic Chemistry
基金
国家自然科学基金资助项目(No.20131020)。
