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聚硫醚型纤维素的合成及其吸附性能 被引量:14

Synthesis and Adsorption Property of Polythioether Cellulose Compound
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摘要 A kind of polythioether cellulose compound(PTEC)was synthesized by etherification of rice husk cellulose with chloromethylthiirane(CMT) in alkaline media. The preparation conditions have been investigated. The PTEC with 4 31% sulfur content was obtained by reacting 12 g rice husk cellulose with 36 mL chloromethylthiirane in 3 mol/L NaOH solution. The product has an adsorption capacity for Ag(Ⅰ) and Hg(Ⅱ) of 24 92 mg/g and 66 80 mg/g, respectively at pH=7 and for Pb(Ⅱ) it is 0 15 mg/g at pH=3. The fiber could be used as a adsorbent for metal ions. A kind of polythioether cellulose compound(PTEC)was synthesized by etherification of rice husk cellulose with chloromethylthiirane(CMT) in alkaline media. The preparation conditions have been investigated. The PTEC with 4 31% sulfur content was obtained by reacting 12 g rice husk cellulose with 36 mL chloromethylthiirane in 3 mol/L NaOH solution. The product has an adsorption capacity for Ag(Ⅰ) and Hg(Ⅱ) of 24 92 mg/g and 66 80 mg/g, respectively at pH=7 and for Pb(Ⅱ) it is 0 15 mg/g at pH=3. The fiber could be used as a adsorbent for metal ions.
机构地区 西北大学化学系
出处 《应用化学》 CAS CSCD 北大核心 2002年第1期94-96,共3页 Chinese Journal of Applied Chemistry
基金 陕西省自然科学基金资助项目 ( 98C2 9)
关键词 稻壳 氯甲基硫杂丙环 金属离子 吸附 聚硫醚型纤维素 合成 废水处理 离子交换纤维素 rice husk cellulose,chloromethylthiirane,metal ion,adsorption
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