期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

三元乙丙橡胶的催化环氧化 被引量：3

CATALYTIC EPOXIDATION OF EPDM
下载PDF
导出
摘要 以叔丁基氢过氧化物为环氧化剂 ,过渡金属化合物三氧化钼为催化剂 ,探讨了三元乙丙橡胶(EPDM)在甲苯中的环氧化反应。通过对反应产物进行核磁共振和红外光谱分析 ,发现即使在高转化率下 ,该反应体系也不存在开环及交联等副反应。分别考察了反应温度、反应时间、氧化剂和催化剂浓度对环氧化反应的影响。 EPDM was successfully epoxidized using t butyhy droperoxide as oxidant in association with molybdenum oxide as catalyst. The resulting polymer was characterized by 1H NMR and FT IR spectrometer, respectively. The result of spectrum analysis showed that no significant side reactions were observed even at high epoxidation level. Moreover, the effects of reaction temperature and the concentrations of oxidant and catalyst on the epoxidation of EPDM were investigated as well.
作者 张莹 陈信忠 张勇 张隐西
机构地区 上海交通大学高分子材料研究所
出处 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2002年第1期59-62,共4页 Polymer Materials Science & Engineering
关键词 催化环氧化 三元乙丙橡胶 叔丁基氢过氧化物 三氧化钼 epoxidation EPDM t butyl hydroperoxide molybdenum oxide
分类号 TQ333.4 [化学工程—橡胶工业]
  • 相关文献

参考文献8

  • 1[1](a)Swern D, Billen G N, Findley T W, et al. J. Am. Chem. Soc., 1945, 67: 1786.(b)Tutorskii I A, Khodzhaeva I D, Novikow S V, et al. Vyskomol. Soedin Ser A, 1973, 15: 2282.(c)Gelling I R. Rubber Chem. & Technol., 1985, 58: 86.(d)Wang X H, Zhang H X, Wang Z G, et al. Polymer, 1997, 38: 5407.
  • 2[2]Sheldon A, Kochi J K. Metal-Catalyzed Oxidations of Organic Compou nds. Academic Press, New York, 1981: 26～33.
  • 3[3]Jian X G, Hay A S. J. Polym. Sci. Part A: Polym. Chem., 1991, 29: 1183.
  • 4[4]Tornaritis M J, Coustsolelos A G. J. Polym. Sci. Part A: Polym. Chem., 1 992, 30: 2791-2795.
  • 5[5]Burfield D R, Lim K L, Law K S, et al. Polymer, 1984, 25: 995.
  • 6[6]Ng S C, Gan L H. Eur. Polym. J., 1981, 17: 1073.
  • 7[7]Herbowski A, Sobczak J M, Zioikowski J J. J. Mol. Catal., 1983, 19: 309.
  • 8[8]Chaumette P, Mimoun H, Saussine L, et al. J. Organometal. Chem. 1983, 250: 291.

同被引文献46

  • 1唐洁,石鸿昌,张治国,王歆燕.在水中由钼(VI)或钨(VI)吡啶醇络合物进行的顺丙烯膦酸的异相催化不对称环氧化[J].有机化学,2006,26(4):508-513. 被引量：2
  • 2Jin G J, Lu G Z, Guo Y L, et al. Modification of Ag-MoO3/ZrO2 catalyst with metallic chloride for propylene epoxidation by molecular oxygen [J]. Catal. Lett., 2004, 97: 191-196.
  • 3Kuhn F E, Santos A M, Goncalves I S, et al. Organorhenium(VII) and organomolybdenum(VI) oxides:Synthesis and application in oxidation catalysis[J]. Appl. Organometal. Chem., 2001, 15: 43-50.
  • 4Freund C, Abrantes M, Kuhn F E. Monomeric cyclopentadiene molybdenum oxides and their carbonyl precursors as epoxidation catalysts[J].J. Organomet. Chem., 2006, 691: 3718-3729.
  • 5Jain K R, Herrmann W A, Kuhn F E. Synthesis and catalytic applications of chiral monomeric organomolybdenum(VI) and organorhenium(VII) oxides in homogeneous and heterogeneous phase[J]. Coordin. Chem. Rev., 2008, 252: 556-568.
  • 6Burke A J. Chiral oxoperoxomolybdenum(VI) complexes for enantioselective olefin epoxidation : Some mechanistic and stereochemical reflections[J]. Coordin. Chem. Rev., 2008, 252: 170-175.
  • 7Jain K R, Ktihn F E. Immobilization of monomefic organometallic molybdenum oxo and carbonyl complexes and their application in epoxidation reactions[J]. Dalton Trans., 2008: 2221-2227.
  • 8Kollar J. Catalytic epoxidation of an olefinically unsaturated compound using an organic hydroperoxide as an epoxidizing agent: US, 3350422[P]. 1967.
  • 9Kollar J. Epoxidation process.- US, 3351635 [P]. 1967.
  • 10Russell J L. Process for producing propylene oxide: US, 3418340[P]. 1968.

引证文献3

二级引证文献3

高分子材料科学与工程
2002年 第1期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部