期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

Li_2CO_3和MnCO_3合成LiMn_2O_4的改进 被引量：1

An improvement of LiMn_2O_4 synthesized from Li_2CO_3 and MnCO_3
下载PDF
导出
摘要 Li2 CO3 和MnCO3 中加入少量柠檬酸或草酸 ,在 5 5 0～ 75 0℃间 ,焙烧 6～ 10h制备了LiMn2 O4 。用TG/DTA ,XRD ,TEM对样品的结构和性质进行了研究。发现在 6 5 0℃焙烧 6h制备的样品具有完整的尖晶石结构 ,样品的平均粒度为 LiMn 2O 4 samples are prepared by heating a mixture of Li 2CO 3, MnCO 3 and C 6H 6O 7H 2O or a mixture of Li 2CO 3, MnCO 3 and H 2C 2O 4·2H 2O in air at 550～750℃ for 6h～10h. Their structure and chemical performance are studied using X-ray diffraciton, TG/DTA and TEM. It has been found that then reaction temperature is at 650℃ for 6h, a well ordered spinel LiMn 2O 4 stucture is produced. Particle sizes of powder are about 40nm.
作者 华黎明 杨志明 王庆杰 徐茂德 魏俊华
机构地区 贵州师范大学化学系 贵州遵义梅岭化工厂
出处 《贵州师范大学学报（自然科学版）》 CAS 2001年第4期43-45,共3页 Journal of Guizhou Normal University：Natural Sciences
基金 贵州省教委资助项目
关键词 LIMN2O4 草酸 柠檬酸 合成 尖晶石结构 碳酸锂 碳酸锰 锂离子电池 正极材料 Spinel LiMn 2O 4,Li 2CO 3, MnCO 3, ethane diacid, citric acid
分类号 O646.54 [理学—物理化学] O614.111 [理学—无机化学]
  • 相关文献

参考文献4

  • 1Ohzuku T., Kiatgawa M., Hirai T., Electrochmistry of manganese dioxide in Lithium nonaqueous cell. Ⅲ. Xray diffractional study on the reduction of spinel-related manganese dioxide[J], J. Electrohem. soc. 1990,1373(3) :769-775.
  • 2Tarascon J. M. , Mckinnon W. R. , Coower F. , et al.Synthesis Conditions and Oxygen Stoichimeter efects on Li imsertion into the LiMn2O4 [J]. J. Electronchem Soc.,1994,141:1421-1426.
  • 3Abraham K. M., Jian2. , A polymer electrolyts-based rechegeable Lithium/oxygen battery [J], J. Electrochem.Soc., 1996,143(1): 1-5.
  • 4X. H. HU, X. P. Ai, H. X. Yang, Sh. X. Li, A Study of LiMn2O4 Synthesized from Li2CO3 and MnCO3 [J]. J. Of power sources, 1998,74:240-243.

同被引文献17

  • 1唐文华,张艾飞,邹洪涛,蒋天智,刘吉平.CdS纳米材料合成方法研究进展[J].贵州师范大学学报（自然科学版）,2006,24(2):119-124. 被引量：3
  • 2Suryakal K,Marikkannu K R,Paruthimal K G,et al.A novel approach to synthesize lithium ion battery spinel cathode materials[J].Ionics,2007,13:41-45.
  • 3Vivekanandhan S,Venkateswarlu M,Satyanarayana N.Novel urea assisted polymeric citrate route for the synthesis of nanocrystalline spinel LiMn2O4 powder[J].J Alloys and Compounds,2007,441(1/2):284-290.
  • 4Hong Y S,Park H B,Yi J E,et al.Characterization of spinel lithium manganite prepared by citrate sol-gel method[J].Bull Korean Chem Soc,1997,18(11):1153.
  • 5Luo J Y,Li X L,Xia Y Y,et al.Synthesis of highly crystalline spinel LiMn2O4 by a soft chemical route and its electrochemical performance[J].Electrochimica Acta,2007,52:4525-4531.
  • 6Huang B J,Santhanam R,Liu D G.Effect of various synthetic parameters on purity of LiMn2O4 spinel synthesized by a sol-gel method at low temperature[J].J Power Sources,2001,101(1):86-89.
  • 7Muhammad J I,Sabia Z.Sythesis and characterization of nanosized lithium manganate and its derivatives[J].J Power Sources,2007,165:393-397.
  • 8Hon Y M,Lin S P,Fung K Z,et al.Sythesis and characterization of nano-LiMn2O4 powder by tartaric acid gel process[J].J European Ceramic Society,2002,22:653-660.
  • 9Zhang Y L,Shin H C,Dong J,et al.Nanostructured LiMn2O4 prepared by glycine-nitrate process for lithium-ion batteries[J].Solid State Ionics,2004,171:25-31.
  • 10PerrinDD 邓新鉴 译.化学反应的隐蔽和解蔽理论和实际应用[M].北京:科学出版社,1976.9-10.

引证文献1

二级引证文献3

贵州师范大学学报（自然科学版）
2001年 第4期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部