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La(ClO_4)_3-BAPOAP-H_2O(30℃)三元体系的相平衡和Ln_2(BAPOAP)_3(ClO_4)_6的合成与表征

Phase Equilibrium of the Ternary System La(ClO_4)_3-BAPOAP-H_2O(30 ℃) and the Syntheses and Characterization of La_2(BAPOAP)_3(ClO_4)_6
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摘要 The phase equilibrium of the ternary system La(ClO\-4)\-3\|BAPOAP\|H\-2O at 30 ℃ was studied by means of the isothermal solubility method. The incongruent compound, La\-2(BAPOAP)\-3(ClO\-4)\-6, was discovered. Based on the results of phase equilibrium, the series compounds Ln\-2(BAPOAP)\-3(ClO\-4)\-6 were synthesized and characterized by chemical analyses, elemental analyses, IR spectra and TG\|DTG analyses. The phase equilibrium of the ternary system La(ClO\-4)\-3\|BAPOAP\|H\-2O at 30 ℃ was studied by means of the isothermal solubility method. The incongruent compound, La\-2(BAPOAP)\-3(ClO\-4)\-6, was discovered. Based on the results of phase equilibrium, the series compounds Ln\-2(BAPOAP)\-3(ClO\-4)\-6 were synthesized and characterized by chemical analyses, elemental analyses, IR spectra and TG\|DTG analyses.
机构地区 西北大学化学系
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2001年第12期1990-1992,共3页 Chemical Journal of Chinese Universities
基金 北京大学稀土材料化学及应用国家重点实验室资助
关键词 高氯酸镧 N N'-二安替比林乙二酰二胺 BAPOAP 三元体系 溶解度 相平衡 合成 镧配合物 表征 Lanthanide perchlorate Lanthanum system \%N,N\%\|Bis(antipyrin\|4\|yl)oxamide Ternary system Solubility Phase equilibrium
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