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超临界二氧化碳微乳液的研究和应用进展 被引量:11

The progress of study and application of supercritical carbon dioxide microemulsion
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摘要 综述了在超临界二氧化碳 (SFC)中 ,能形成微乳液的表面活性剂 (SAA)的结构特性 ,助SAA对SFC微乳液形成的影响以及SFC微乳液的研究现状。同时 ,介绍了紫外 -可见吸收光谱、傅立叶 -红外光谱、小角中子散射和小角X光散射等近代测试方法 ,及其在SFC微乳液形成及其结构特性研究中的应用。另对SFC微乳液在化学反应、生物活性物质及金属离子萃取。 The structure properties of surfactants,which can form supercritical carbon dioxide microemulsions and the effect of cosurfactant on the formation of supercritical carbon dioxide microemulsion are reviewed.Meanwhile,the application of current method of determination such as ultraviovisiblc absorbancc spcctroscopy,fouricr-transform infrarcd spcctroscopy,small-anglc ncutron scattcring and smallangle x-ray scattering to the study of formation and structure properties of supercritical carbon dioxide microemulsion are introduced.Moreover,the application of supercritical carbon dioxide microemulsions to the field of chemical reaction,extraction of biochemicals and metal ions,synthesis of materials and cleaning are also introduccd.
出处 《日用化学工业》 CAS CSCD 北大核心 2002年第1期31-34,共4页 China Surfactant Detergent & Cosmetics
基金 国家自然科学基金资助项目 (2 972 530 )
关键词 超临界二氧化碳 微乳液 表面活性剂 助表面活性剂 SFC SAA supcrcritical carbon dioxidc microcmulsion surfactant cosurfactant
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  • 1K. A. Consani, R. D. Smith. Observations on the solubility of sur- factants and related molecules in carbon diocide at 50 ℃ [ J ]. Supercritical Fluids, 1990, 3: 51.
  • 2J. M Ritter, M. E. Paulaitis. In supercritical fluid science and technology [ C]. Washington, DC.: Amcrican Chcmical Socicty, ACS Symp. Ser. No. 406.
  • 3Dandge D. K, Heller J. P., Wilson, K. V.. Structure solubility correlations: organic compounds and dense carbon dioxide binary systems[J]. Ind. Eng. Chem. Prod. Res. Dev., 1985, 24: 162.
  • 4HocflingT. A, Bcitlc. R. R, Enick R. M. Bcckman, E. J. Dcsign and synthesis of highly CO2-solublc surfactants and chelatng agents[J]. 1993, 83: 203.
  • 5Hoefling T. A. Enick R. M. Beckman E. J. Microemulsions in near -critical and supercritical CO2 [J]. J. Phys. Chcm. 1991, 95: 7127-7129.
  • 6Mcfann. G. J. Johnston. K. P. Solubilization in nonionic rcvcrsc micollesin carbon dioxide [J]. AIChE Journal, 1994, 40 (3): 543 -555.
  • 7Johnston. K. P. Harrison. K. L Clarke. M. J. Water-in- carbon dioxide mieroemulsions: an environment for hydrophilcs including protcins[J]. Scicncc, 1996, 271 (2): 624-626.
  • 8Harrison. K Goveas J Johnston. K. P. Water-in-carbon dioxide mi- croemulsions with a fluorocarbon-hydrocarbon hybrid surfactant[ J ].Langmuir, 1994, 10: 3536-3541.
  • 9Ito. A., Sakai H Kondo. Y. Micellar Solution properties of fluorocarbon-hydrocarbon hybrid surfactants [J]. Iangmuir, 1996, 12:5768 -5772.
  • 10Eastoe. J., Steytler. D. C. Droplet structure in a water- in- CO2 Microemulsion[J]. Langmuir, 1996, 12: 1423-1424.

同被引文献224

  • 1苑世领,吴锐,蔡政亭.水溶液中嵌段共聚物的耗散颗粒动力学模拟[J].物理化学学报,2004,20(8):811-815. 被引量:18
  • 2张腾云,钟理.超临界二氧化碳中的胶束催化技术进展[J].化工进展,2004,23(9):948-952. 被引量:1
  • 3唐正贵,张车文,乐以伦.二缩水甘油醚的一步合成[J].化学试剂,1994,16(2):107-109. 被引量:5
  • 4李淑芬.超临界CO2萃取天然产品的特性研究[A]..全国超临界流体技术学术及应用研讨会论文集[C].北京:清华大学出版社,1996.30-35.
  • 5CONSAN K A, SMITH R D. Observations on the solubility of surfactants and related molecules in carbon dioxide at 50 ℃ [ J ]. The Journal of Supercritical Fluids, 1990,3 (2) :51-65.
  • 6SALANIWAL S, CUI S T, COCHRAN H D, et al. Molecular simulation of a dichain surfactant/water/carbon dioxide system. 1. Structural properties of aggregates [J]. Langmuir,2001,17(5) : 1773-1783.
  • 7LU L, BERKOWITZ M L. Molecular dynamics simulation of a reverse micelle self assembly in supercritical CO2 [J]. J AM CHEM SOC,2004, 126(33) :10254-10255.
  • 8LISAL M, HALL C K, GUBBINS K E. Self-assembly of surfactants in a supercritical solvent from lattice Monte Carlo simulations [ J ]. Journal of Chemical Physics,2002,116(3) :1171-1184.
  • 9SCANU L F, GUBBINS K E, HALL C K. Simulations of phase separation and micellization in super critical CO2/ surfaetant systems: effect of CO2 density [ J]. Langmuir, 2004, 20(2) :514-523.
  • 10LI Zhengmin, HALL C K. Phase behavior in model homopolymer/CO2 and surfactant/CO2 systems: discontenuous molecular dynamics simulations [ J ]. Langmuir, 2004,20(20) :8559-8568.

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