Cu(Ⅰ)(CH_3COCHCOOEt)[P(NEt_2)_3]_2配合物的电化学合成及表征

Electrochemical Synthesis and Characterization of Copper(Ⅰ) Complexes with Ethylacetoacetate and Hexaethylophosphorus Triamide

用牺牲金属阳极的电化学方法合成了一种新的一价铜配合物 Cu( ) (CH3COCHCOOEt) [P(NEt2 ) 3]2 ,对配合物进行了元素分析、红外光谱、核磁共振测试及表征 ,并研究了反应的机理 .

The complexes of Cu(Ⅰ) with ethylacetoacetate and hexaethylophosphorus triamide were prepared by an electrochemical method in nonaqueous solvents. The product was characterized by elemental analysis, IR, 1H and 13 C NMR measurements as Cu(Ⅰ)(CH 3COCHCOOEt)[P(NEt 2) 3] 2. The mechanism of the electrochemical reactions is studied here.