摘要
综述了手性双唑啉配体的主要结构类型 ,并讨论了手性双唑啉铜配合物在不对称Diels Alder反应、Ene反应、Mukaiyamaadol反应、烯丙基氧化、环丙烷化、氮杂环丙烷化等反应中的应用。
The kinds of chiral bis\|oxazoline ligands and catalysts were summarized and the activities of catalysts were compared.The application of chiral bis\|oxazoline copper complexes to the asymetric Diels\|alder reaction,ene reaction allylic oxidation,cyclopropanation of olefins and aziridination of olefins were also discussed.
出处
《化学通报》
CAS
CSCD
北大核心
2001年第10期614-620,共7页
Chemistry
关键词
双E唑啉
手性双E唑啉酮配合物
不对称合成
配体
应用
C\-2\|symmetric, Bis\|oxazoline, Chiral bis\|oxazoline copper complexes, Asymmetric synthesis
