二正丁基锡双(二茂铁硫代甲酸酯)配合物的红外光谱和核磁共振谱

Study on Di-n-butyl Tin Bis-ferrocenethioformate by IR and NMR (~1H, ^(13)C and ^(119)Sn) Spectroscopy

合成了二正丁基锡新型配合物(n_Bu)2Sn(FcCOS)2[Fc= (η_C5H5)Fe(1_5_η_C5H4)—] ;研究了该配合物的红外光谱和核磁共振(1H、13C、119Sn)谱 。

A novel complex of di _ n _ butyl tin bis _ ferrocenethioformate(n _ Bu)2 Sn(FcCOS)2 was synthesized by the reaction of (n _ Bu)2 SnO with FcCOSH [(Fc=η _ C5H5)Fe(1 _ 5 _ η _ C5H4)-]. Its IR and NMR(1H, 13C and 119Sn) spectral data were studied, and its possible molecular structure was suggested.