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金属离子Cr^(3+)在染黑色革中的应用 被引量:1

Application of Metal Ion Cr^(3+) in Dyeing Black Leather
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摘要 本文通过分光光度法 ,pH电位滴定等分析方法研究了金属离子Cr3+与常用黑色染料的作用机理。结果表明 :皮革染色中加入金属离子Cr3+,可以改变染料溶液的性质 ;染料的活性基团、皮胶原纤维活性基团与金属离子形成了混合络合物。 In this paper, action mechanisms on metal ion (Cr 3+ ) and the conventional black dyestuffs were investigated through the spectrophometric method & pH potentrionmetric titration. The result showed the addition of metal ion (Cr 3+ ) during the dyeing step may change the properties of dyeing bath. The functional groups of the penetrated dyestuff and hide fiber could form the mixed complex with metal ion, which improved the fastness to rubbing
出处 《皮革化工》 2002年第1期32-34,43,共4页 Leather Chemicals
关键词 铬离子 金属离子 皮革 染色 应用 黑色 metal ion Cr 3+ leather dyeing application
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参考文献2

  • 1张廷有.皮革染色基础[M].北京:科学出版社,1999..
  • 2吴冠英.梁整工艺学(第三册)[M].北京:纺织工业出版社,1993..

同被引文献8

  • 1栾世方,范浩军,孙兵.铬鞣助剂OXD-I的应用工艺优化及高吸收铬鞣机理研究[J].中国皮革,2006,35(7):29-33. 被引量:17
  • 2Sundarapandiyan S, Brutto P E, Siddhar- tha G, et al. Enhancement of chromium uptake in tanning using oxazolidine [ J ]. Journal of Hazardous Materials ,2011,190 ( 1 - 3 ) :802 - 809.
  • 3Covington D,Lampard G S, Menderes O, et al. Extended X - ray absorption fine structure studies of the role of chromium in leather tanning[ J]. Polyhedron,2001, 20(5) :461 -466.
  • 4Morera J M, Esther B, Roberto C, et al. Minimization of the environmental impact of chrome tanning: a new process reusing the tanning floats [ J ]. Journal of Cleaner Production,2011,19( 17 - 18 ) :2 128 - 2 132.
  • 5Rao J R, Balasubramanian E, Padmalatha C, et al. Recovery and reuse of chromium from semichrome liquors [ J ]. Journal of the American I-e.ather Chemists Associa- tion,2002,97(3) :106 - 113.
  • 6Kanagaraj J, Chandra B N, Mandal A B. Recovery and reuse of chromium from chrome tanning waste water aiming to- wards zero discharge of pollution [ J ]. Clean production, 2008, 16 ( 16 ) : 1 807 - 1 813.
  • 7Zhou J, Hu S X,Wang Y N,et aL Release of chrome in chrome tanning and post tanning processes EJ]. Journal of the So- ciety of Technologists and Chemists,2012,96(4) : 157 - 162.
  • 8张彪,苗青,金勇.铬鞣高吸收助剂的研究进展[J].皮革科学与工程,2009,19(6):28-34. 被引量:9

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