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甘氨酸燃烧合成YAG∶Tb荧光粉的微观结构和发光特性 被引量:9

Microstructure and Luminescent Properties of Tb Doped YAG Phosphor by Combustion Synthesis with Glycine
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摘要 Luminescent terbium doped yttrium aluminum garnet (YAG∶Tb) powders were prepared using yttrium and aluminum oxide precursor particles produced by combustion process with glycine. Heat treatment of the resulting precursor powders at 950℃or 1450℃for 2h, yielded pure YAG particles. The morphology of YAG∶Yb phosphor after sintering at 1450℃appeared to be spherical or elliptical and the grain size of the phosphor was in the range of 0.6 to 1.4μm. From the photoluminescence spectra, transitions 5D4 7FJ corresponding to Tb3+in YAG matrices were identified. The prominent transition 5D4 7F6 emission for YAG∶0.05Tb phosphor after sintering at 1450℃was very significant to improve the chromaticity of YAG∶Tb phosphor. Luminescent terbium doped yttrium aluminum garnet (YAG∶Tb) powders were prepared using yttrium and aluminum oxide precursor particles produced by combustion process with glycine. Heat treatment of the resulting precursor powders at 950℃or 1450℃for 2h, yielded pure YAG particles. The morphology of YAG∶Yb phosphor after sintering at 1450℃appeared to be spherical or elliptical and the grain size of the phosphor was in the range of 0.6 to 1.4μm. From the photoluminescence spectra, transitions 5D4 7FJ corresponding to Tb3+in YAG matrices were identified. The prominent transition 5D4 7F6 emission for YAG∶0.05Tb phosphor after sintering at 1450℃was very significant to improve the chromaticity of YAG∶Tb phosphor.
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2002年第4期431-434,共4页 Chinese Journal of Inorganic Chemistry
基金 河北省自然科学基金资助项目(No.299193)。
关键词 YAG Tb 发光 燃烧合成 微观结构 甘氨酸 助燃剂 稀土荧光粉 掺杂 YAG∶Tb luminescence combustion synthesis microstructure
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