摘要
Coexisting arsenic(As) and antimony(Sb) in mining wastewater is a common and great concern. On-site simultaneous removal of As and Sb from mining wastewater was achieved by using a reusable granular TiO_2 column in this study. To evaluate the accuracy of the scale-up procedure, As and Sb adsorption from wastewater was studied in both large(600 g TiO_2) and small columns(12 g TiO_2) based on the proportional diffusivity rapid small-scale column tests(PD-RSSCTs) design. The comparable As and Sb breakthrough curves obtained from small and large columns confirmed the accuracy of the PD-RSSCT theory in the design of large-scale columns. Meanwhile, the consistent As and Sb adsorption results from batch and column experiments suggested that TiO_2 adsorption for As and Sb can be predicted from bench-scale tests. Charge distribution multi-site complexation(CD-MUSIC) and onedimensional transport modeling integrated in the PHREEQC program were performed to study the adsorption behaviors of As and Sb on the TiO_2 surface. Coexisting ions, such as Ca^(2+), Mg^(2+), and Si^(4+), play an important role in As and Sb adsorption, and the breakthrough curves were well simulated after considering the compound ion effects. The results from this study highlight the surface reactions of As and Sb on TiO_2 and provide a practical way for on-site remediation of industrial wastewater.
Coexisting arsenic(As) and antimony(Sb) in mining wastewater is a common and great concern. On-site simultaneous removal of As and Sb from mining wastewater was achieved by using a reusable granular TiO_2 column in this study. To evaluate the accuracy of the scale-up procedure, As and Sb adsorption from wastewater was studied in both large(600 g TiO_2) and small columns(12 g TiO_2) based on the proportional diffusivity rapid small-scale column tests(PD-RSSCTs) design. The comparable As and Sb breakthrough curves obtained from small and large columns confirmed the accuracy of the PD-RSSCT theory in the design of large-scale columns. Meanwhile, the consistent As and Sb adsorption results from batch and column experiments suggested that TiO_2 adsorption for As and Sb can be predicted from bench-scale tests. Charge distribution multi-site complexation(CD-MUSIC) and onedimensional transport modeling integrated in the PHREEQC program were performed to study the adsorption behaviors of As and Sb on the TiO_2 surface. Coexisting ions, such as Ca^(2+), Mg^(2+), and Si^(4+), play an important role in As and Sb adsorption, and the breakthrough curves were well simulated after considering the compound ion effects. The results from this study highlight the surface reactions of As and Sb on TiO_2 and provide a practical way for on-site remediation of industrial wastewater.
基金
supported by the National Basic Research Program (973) of China (No.2015CB932003)
the Strategic Priority Research Program of the Chinese Academy of Sciences (No.XDB14020201)
the National Natural Science Foundation of China (Nos.41373123,41425016,and 21321004)
