钛、镍、铁配合物在硅氢加成反应中的应用

Application of the Tianium, Nickel and Iron Complexes in the Hydrosilylation

Ti、Ni、Fe配合物作为催化剂广泛应用于有机催化反应中,表现出良好的催化性能,是有机金属催化化学的研究热点之一。本文介绍了近年来非贵金属钛、镍、铁配合物作为催化剂在烯炔烃、含羰基化合物及其他不饱和双键、三键化合物硅氢加成反应中的应用研究成果和进展,分析了这三类催化剂在使用过程中存在的不足,并对其作为催化剂的应用前景进行了展望。

Tianium, nickel and iron complexes as catalysts have been widely applied in numerous catalytic organic reactions, in which these complexes show excellent catalytic performance and have been recognized as very important research field. We summarize the recent progress in the synthesis of titanium, nickel and iron complexes and their application in the catalytic hydrosilylation of alkenes, alkynes, carbonyl compounds and other unsaturated double bond, triple bond compounds. Furthermore, the deficiencies of the catalysts have been discussed. At last, the future development and prospects of these complexes as catalysts are also proposed.