摘要
本文测定了苯甲亚氨酸乙酯(Ⅰ)和N-乙氧基羰基亚甲基苯甲亚氨酸乙酯(Ⅱ)的~1H和^(13)C NMR谱,归属了共振谱线,得到了这两类化合物的官能团在苯衍生物中的经验增量,讨论了化学位移与Hammett常数的相关性.
1H and 13C NMR spectra of ethyl benzenecarboximidates (Ⅰ) and ethyl N -(ethoxycarbonylmethyl) benzenecarboximidates (Ⅱ) were determined. The resonance lines of these compounds were assigned, and the empirical substituent increments of Et were obtained. It was found that there
were some linear relationships between chemical shifts and Hammett constants σ.
出处
《波谱学杂志》
CAS
CSCD
1989年第3期306-306,共1页
Chinese Journal of Magnetic Resonance
基金
国家自然科学基金资助项目
关键词
亚氨酸酯
NMR
取代基
增量
Imidate
NMR
Chemical shift
Substituent increment
Hammctt constant.
