角重叠模型的基本原理和化学应用

Fundamental principles and chemical applications of angular overlap model

本文介绍了描述配合物电子结构的角重叠模型。在阐明基本假设和基本参数的计算方法后,重点说明了该模型在推断MLn配合物几何构型方面的应用。

An angulap overlap model which describes electronic structures of coordination compounds is presented.After introducing principal postulates and calculatiag mathod of fundamenta 1 parameters, applications of the model in prediction of the geometrical configurations of MLn coordination compounds have been emphasized.